How FirstCheck+ PID Works
FirstCheck+ measures volatile organic compounds in air by photoionisation detection (PID), which is shown schematically in the figure below. Test gas
is drawn into the chamber from the FirstCheck+ probe. It is caused by the chamber design to move across the face of a lamp window, emitting light particles, or photons (shown by arrows) of high UV energy. Essential for the detection of a molecule XY is photoionisation
, which occurs when a photon is adsorbed
by the molecule, generating two electrically charged fragments, or ions,
, one positively charged, X+, and one negatively charged, Y-. An electric field between two metal grids, called electrodes, attracts ions towards them. At the electrodes, ions are neutralised by movement of a tiny electric current, the photoionisation current, which is proportional to the concentration of XY, so that it can be amplified and displayed as a gas concentration. FirstCheck+ contains a third, fence electrode, patent pending, to ensure that the amplified current does not include a significant current due to other causes, such as water condensation on the chamber walls. Exhaust gas
is removed from the chamber by means of a pump inside the FirstCheck+ housing.

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